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doi: 10.1016/j.envexpbot.2016.10.004 41 GilroyS.BiaasekM.SuzukiN.GreckaM.DevireddyA
PMID 4980931
In enzymatic reactions, phenolic substances undergo oxidation to form quinones, which are subsequently transformed into melanin, resulting in brown appearance on products (48)
However, a small fraction of APAP undergoes oxidative metabolism by cytochrome P450 enzymes, predominantly cytochrome P450 2E1 (CYP2E1), to form N-acetyl-p-benzoquinone imine (NAPQI), a highly reactive and toxic intermediate
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