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Whilst NAC does convert to glutathione and could be why NAC has its benefits, both antioxidants play important roles in your body

Plasma homocysteine and severity of atherosclerosis in young patients with lower-limb atherosclerotic disease

(8) The liver can even make its own glutathione to support itself

In the lower range of values of S , GSH increases rapidly as S increases

The combination of three methyl donors - SAM, folate, betaine (Figure 2) - alleviated alcoholic liver injury, while at the same time lowering the elevated SAM / SAH ratio and homocysteine level (114), but the aforesaid evidence also points to the critical importance of ascorbic acid in protecting the exocrine pancreas, as shown by its ameliorating effect in animal models of mild and severe pancreatitis (30)