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The peptide backbone provides three coordination sites for copper: the free alpha-amino group of glycine, the deprotonated amide nitrogen of the glycyl-histidyl bond, and the imidazole nitrogen of the histidine side chain, with the lysine epsilon-amine remaining available for further interactions

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Informed consent was obtained from all patients and approvals were obtained from the Ethics Committee of Tongji Hospital, Tongji University for the use of these specimens in research